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Multivariate analysis of single-molecule spectra: surpassing spectral diffusion.

作者信息

Hofmann Clemens, Michel Hartmut, van Heel Marin, Köhler Jürgen

机构信息

Experimental Physics IV and BIMF, University of Bayreuth, Germany.

出版信息

Phys Rev Lett. 2005 May 20;94(19):195501. doi: 10.1103/PhysRevLett.94.195501. Epub 2005 May 16.

Abstract

The full exploitation of single-molecule spectroscopy in disordered systems is often hampered by spectral diffusion processes of the optical transitions due to structural fluctuations in the local environment of the probe molecule which leads to temporal averaging of the signal. Multivariate statistical pattern recognition techniques, originally developed for single-molecule cryoelectron microscopy, allow us to retrieve detailed information from optical single-molecule spectra. As an example, we present the phonon side band of the B800 excitations of the light-harvesting 2 (LH2) complex from Rhodospirillum molischianum, revealing the electron-phonon coupling strength for these transitions. The measured Debye-Waller factors, ranging from 0.4 to 0.9, fall in the regime of weak electron-phonon coupling.

摘要

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