Wehner Stefan, Hoffmann Patrick, Schmeisser Dieter, Brand Helmut R, Küppers Jürgen
Experimentalphysik III, Universität Bayreuth, 95440 Bayreuth, Germany.
Phys Rev Lett. 2005 Jul 15;95(3):038301. doi: 10.1103/PhysRevLett.95.038301. Epub 2005 Jul 11.
The rate of CO oxidation on Ir(111) surfaces exhibits bistability at T=500 K in a range of the CO fraction Y in the CO+O reactant gas flux. Measured CO2 rates as a function of the noise strength imposed on Y are well reproduced by parameter-free modeling. We present photoelectron emission microscopy measurements and 2D calculations of the spatiotemporal patterns of CO- and O-rich domains. The role of combined multiplicative and additive noise on Y for CO and O domain wall motion and island nucleation-growth-coalescence processes is analyzed.