硫腙的有机锡（IV）配合物：合成、表征及抗真菌研究
Organotin(IV) complexes of thiohydrazones: synthesis, characterization and antifungal study.
作者信息
Mishra A K, Manav N, Kaushik N K
机构信息
Department of Chemistry, University of Delhi, Delhi-110007, India.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2005 Oct;61(13-14):3097-101. doi: 10.1016/j.saa.2004.11.035. Epub 2005 Jan 18.
Some new organotin(IV) complexes with salicylaldehyde aniline-N-thiohydrazone (L1) and cinamaldehyde aniline-N-thiohydrazone (L2) of the type (p-ClC6H4)3Sn[L] Cl and (p-ClC6H4)2Sn[L]Cl2 have been synthesized (where L = L1 and L2). The complexes and ligands were characterized by elemental analysis and spectral (UV-vis, IR and 1H NMR) studies. In all the complexes, ligands act as bidentate, coordination through sulphur and azomethane nitrogen. Complexes are 1:1 metal ligands complexes. Antifungal studies of some complexes against Rhizoctonia bataticola fungal strain have been carried out.
已合成了一些新型的有机锡（IV）配合物，其类型为（对氯苯基）3Sn[L]Cl和（对氯苯基）2Sn[L]Cl2，其中L为水杨醛苯胺-N-硫腙（L1）和肉桂醛苯胺-N-硫腙（L2）（L = L1和L2）。通过元素分析和光谱（紫外可见、红外和1H核磁共振）研究对配合物和配体进行了表征。在所有配合物中，配体作为双齿配体，通过硫和偶氮甲烷氮进行配位。配合物为1:1金属-配体配合物。已对一些配合物针对茄丝核菌真菌菌株进行了抗真菌研究。
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