Köse Muhammet Erkan, Omar Ahmed, Virgin Christopher A, Carroll Bruce F, Schanze Kirk S
Department of Chemistry and Department of Mechanical and Engineering Science, University of Florida, P. O. Box 117200, Gainesville, FL 32611, USA.
Langmuir. 2005 Sep 27;21(20):9110-20. doi: 10.1021/la050999+.
Oxygen sensor films are frequently used to image air-pressure distributions on surfaces in aerodynamic wind tunnels. In this application, the sensor film is referred to as a pressure-sensitive paint (PSP). A Stern-Volmer calibration is used to relate the emission intensity ratio of a long-lifetime luminescent dye (the pressure-sensitive luminophore, PSL) to surface air pressure. A major problem in PSP measurements arises because the Stern-Volmer calibration of the PSL's emission varies with temperature. To correct for the temperature dependence, a second luminescent dye that has an emission that varies with temperature (the temperature-sensitive luminophore, TSL) is incorporated into the sensor film. With such a dual-luminophore PSP (DL-PSP), it is possible to measure the surface-temperature distribution with the TSL emission, and this information is then used to correct the temperature dependence of the PSL's pressure response. In the present article, we report the application of a DL-PSP to obtain high-resolution air-pressure distributions on a surface that is subjected to a 20 degrees C temperature gradient. Two different calibration methods are used to generate surface-temperature and air-pressure distributions from the luminescence imaging data, and a quantitative comparison of the results obtained from the two methods is provided. The first method is based on an intensity-ratio calibration that uses luminescence images collected at two wavelengths, one corresponding to the TSL emission and the second corresponding to the PSL emission. The second method is based on principal component analysis (PCA) of luminescence images obtained at four wavelengths throughout the spectral region of the TSL and PSL emission (hyperspectral imaging, 550-750 nm). The results demonstrate that the PCA method allows the measurement of surface air pressure with higher accuracy and precision compared to those of the intensity-ratio method. The improvement is especially significant at pressures near 1 atm, where the temperature interference is most pronounced. Surface-pressure distributions are measured with comparable accuracy and precision with the two methods.
氧传感器薄膜常用于在空气动力学风洞中对表面的气压分布进行成像。在这种应用中,传感器薄膜被称为压敏漆(PSP)。采用斯特恩 - 沃尔默校准来关联长寿命发光染料(压敏发光体,PSL)的发射强度比与表面气压。PSP测量中的一个主要问题是,PSL发射的斯特恩 - 沃尔默校准会随温度变化。为了校正温度依赖性,将一种发射随温度变化的第二种发光染料(温度敏感发光体,TSL)掺入传感器薄膜中。使用这种双发光体PSP(DL - PSP),可以通过TSL发射测量表面温度分布,然后利用该信息校正PSL压力响应的温度依赖性。在本文中,我们报告了DL - PSP在一个承受20℃温度梯度的表面上获取高分辨率气压分布的应用。使用两种不同的校准方法从发光成像数据生成表面温度和气压分布,并对两种方法获得的结果进行了定量比较。第一种方法基于强度比校准,使用在两个波长收集的发光图像,一个对应于TSL发射,另一个对应于PSL发射。第二种方法基于在TSL和PSL发射的整个光谱区域(550 - 750nm高光谱成像)的四个波长处获得的发光图像的主成分分析(PCA)。结果表明,与强度比方法相比,PCA方法能够以更高的准确度和精度测量表面气压。在接近1个大气压的压力下,这种改进尤为显著,因为此时温度干扰最为明显。两种方法测量表面压力分布的准确度和精度相当。