配位化合物的开环聚合：一种兼具环状和聚合物组分的银（I）网络。

Ring-opening polymerisation of coordination compounds: a silver(I) network with both ring and polymer components.

作者信息

Yue Nancy L S, Jennings Michael C, Puddephatt Richard J

机构信息

Department of Chemistry, University of Western Ontario, London, Canada.

出版信息

Chem Commun (Camb). 2005 Oct 14(38):4792-4. doi: 10.1039/b510080a. Epub 2005 Aug 31.

DOI:10.1039/b510080a

PMID:16193116

Abstract

The terpyridyl ligand 2,6-C5H3N{C(=O)N(Me)-4-C5H4N}2, 1, combined with silver(I) salts to give the complexes [Ag2(1)2][BF4]2, 2, and [{Ag3(1)2}n][CF3SO3]3n, 3; the network structure of complex contains both macrocyclic units [Ag2(mu-1)2]2+ and ring-opened polymeric units [{Ag(mu-1)}n]n+.

摘要

三联吡啶配体2,6-C5H3N{C(=O)N(Me)-4-C5H4N}2（1）与银（I）盐反应生成配合物[Ag2(1)2][BF4]2（2）和[{Ag3(1)2}n][CF3SO3]3n（3）；配合物的网络结构包含大环单元[Ag2(μ-1)2]2+和开环聚合物单元[{Ag(μ-1)}n]n+。