Sirtori Carla, Altvater Priscila K, de Freitas Adriane M, Peralta-Zamora Patricio G
Chemistry Department, Federal University of Paraná, P.O. Box 19081, 81531-990 Curitiba-PR, Brazil.
J Hazard Mater. 2006 Feb 28;129(1-3):110-5. doi: 10.1016/j.jhazmat.2005.08.017. Epub 2005 Oct 10.
In this study the photocatalytic degradation of aqueous solutions of camphor was investigated by using TiO2 and ZnO photocatalysts. In the presence of artificial UV-light the highly photosensitive camphor was almost totally degraded after reaction times of 60 min. However, under these conditions the mineralization degree was lower than 25%. In the presence of semiconductors the degradation was complete after a treatment time of about 30 min. Moreover, the mineralization was considerably greater, mainly with the use of TiO2 (> 80% at reaction time of 60 min). Heterogeneous photocatalytic processes applied in the presence of solar radiation show a promising degradation capability. TiO2-based processes afforded mineralization degrees of about 90% after a reaction time of 120 min, when the system was assisted by aeration.
在本研究中,使用二氧化钛(TiO₂)和氧化锌(ZnO)光催化剂研究了樟脑水溶液的光催化降解。在人工紫外光存在下,高感光性的樟脑在反应60分钟后几乎完全降解。然而,在这些条件下,矿化度低于25%。在半导体存在的情况下,处理约30分钟后降解完成。此外,矿化程度显著提高,主要是使用TiO₂时(在60分钟反应时间时>80%)。在太阳辐射存在下应用的多相光催化过程显示出有前景的降解能力。当系统通过曝气辅助时,基于TiO₂的过程在反应120分钟后矿化度达到约90%。