16π八烷基四苯基卟啉的合成与结构

Synthesis and structure of 16 pi octaalkyltetraphenylporphyrins.

作者信息

Yamamoto Yohsuke, Yamamoto Akihiro, Furuta Shin-ya, Horie Masanori, Kodama Megumi, Sato Wataru, Akiba Kin-ya, Tsuzuki Seiji, Uchimaru Tadafumi, Hashizume Daisuke, Iwasaki Fujiko

机构信息

Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan.

出版信息

J Am Chem Soc. 2005 Oct 26;127(42):14540-1. doi: 10.1021/ja052842+.

DOI:10.1021/ja052842+

PMID:16231884

Abstract

The oxidized octaethyltetraphenylporphyrin (1, OETPP) and the corresponding newly prepared octaisobutyltetraphenylporphyrin (3, OisoBuTPP) could be isolated from the reaction of OETPPLi2 (or OisoBuTPPLi2) with SOCl2. The X-ray analysis and the characteristic UV-vis spectra of 1 and 3 revealed that these are the first examples of 16 pi nonaromatic porphyrins.

摘要

氧化八乙基四苯基卟啉（1，OETPP）和相应新制备的八异丁基四苯基卟啉（3，OisoBuTPP）可从OETPPLi2（或OisoBuTPPLi2）与SOCl2的反应中分离得到。1和3的X射线分析及特征紫外可见光谱表明，它们是16π非芳香卟啉的首例。