Král Petr, Seideman Tamar
Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, USA.
J Chem Phys. 2005 Nov 8;123(18):184702. doi: 10.1063/1.2107527.
We show that electric current running through a nanojunction with a biased helical molecule can induce unidirectional rotation of the molecular component. In an electric field, conduction electrons injected into the molecule are accelerated along the helical path going through its body, thereby gaining directed angular momentum. Conservation laws require that an angular momentum of the same size but opposite sense is imparted to the rigid-body rotation of the helix. We describe the angular momentum exchange processes that underlie the operation of the nanorotor, discuss factors limiting its efficiency, and propose potential applications.
我们表明,通过带有偏置螺旋分子的纳米结的电流可诱导分子组件的单向旋转。在电场中,注入分子的传导电子沿着穿过其主体的螺旋路径加速,从而获得定向角动量。守恒定律要求将大小相同但方向相反的角动量赋予螺旋体的刚体旋转。我们描述了纳米转子运行所基于的角动量交换过程,讨论了限制其效率的因素,并提出了潜在应用。