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红肉猕猴桃(中华猕猴桃和美味猕猴桃)果实中的色素。

Pigments in the fruit of red-fleshed kiwifruit (Actinidia chinensis and Actinidia deliciosa).

作者信息

Montefiori Mirco, McGhie Tony K, Costa Guglielmo, Ferguson A Ross

机构信息

Dipartimento di Colture Arboree, Università di Bologna, Viale Fanin 46, 40127 Bologna, Italy.

出版信息

J Agric Food Chem. 2005 Nov 30;53(24):9526-30. doi: 10.1021/jf051629u.

Abstract

Kiwifruit cultivars (Actinidia chinensis and A. deliciosa) generally have fruit with yellow or green flesh when ripe. A small number of genotypes also have red pigments, usually restricted to the inner pericarp but varying in intensity and in distribution within the fruit. Carotenoids, chorophylls, and anthocyanins were extracted from the fruit pericarp of such red-fleshed kiwifruit selections. Pigments were analyzed by HPLC and identified by comparison with authentic standards and by liquid chromatography-mass spectroscopy to obtain a tentative identification of the major anthocyanins in red-fleshed kiwifruit. The yellow and green colors of the outer fruit pericarp are due to different concentrations and proportions of carotenoids and chlorophylls. The red color found mainly in the inner pericarp is due to anthocyanins. In the A. chinensis genotypes tested the major anthocyanin was cyanidin 3-O-xylo(1-2)-galactoside, with smaller amounts of cyanidin 3-O-galactoside. In the A. deliciosa genotypes analyzed, cyanidin 3-O-xylo(1-2)-galactoside was not detected; instead, the major anthocyanins identified were cyanidin 3-O-galactoside and cyanidin 3-O-glucoside. However, the two species did not differ consistently in anthocyanin composition.

摘要

猕猴桃品种(中华猕猴桃和美味猕猴桃)成熟时果实通常具有黄色或绿色果肉。少数基因型也含有红色素,通常仅限于内果皮,但在果实中的强度和分布有所不同。从此类红肉猕猴桃选种的果实果皮中提取了类胡萝卜素、叶绿素和花青素。通过高效液相色谱法(HPLC)分析色素,并与标准品进行比较以及通过液相色谱 - 质谱联用进行鉴定,以初步鉴定红肉猕猴桃中的主要花青素。果实外果皮的黄色和绿色是由于类胡萝卜素和叶绿素的浓度及比例不同。主要在内果皮中发现的红色是由于花青素。在所测试的中华猕猴桃基因型中,主要花青素为矢车菊素3 - O - 木糖(1 - 2) - 半乳糖苷,还有少量矢车菊素3 - O - 半乳糖苷。在分析的美味猕猴桃基因型中,未检测到矢车菊素3 - O - 木糖(1 - 2) - 半乳糖苷;相反,鉴定出的主要花青素是矢车菊素3 - O - 半乳糖苷和矢车菊素3 - O - 葡萄糖苷。然而,这两个物种在花青素组成上并非始终存在差异。

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