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二维半柔性聚合物的弹性

Elasticity of semiflexible polymers in two dimensions.

作者信息

Prasad Ashok, Hori Yuko, Kondev Jané

机构信息

Martin Fisher School of Physics, Brandeis University, Mailstop 057, Waltham, Massachusetts 02454-9110, USA.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2005 Oct;72(4 Pt 1):041918. doi: 10.1103/PhysRevE.72.041918. Epub 2005 Oct 18.

Abstract

We study theoretically the entropic elasticity of a semiflexible polymer, such as DNA, confined to two dimensions. Using the worm-like-chain model we obtain an exact analytical expression for the partition function of the polymer pulled at one end with a constant force. The force-extension relation for the polymer is computed in the long chain limit in terms of Mathieu characteristic functions. We also present applications to the interaction between a semiflexible polymer and a nematic field, and derive the nematic order parameter and average extension of the polymer in a strong field.

摘要

我们从理论上研究了限制在二维空间中的半柔性聚合物(如DNA)的熵弹性。使用蠕虫状链模型,我们得到了一端以恒定力拉伸的聚合物配分函数的精确解析表达式。聚合物的力-伸长关系是在长链极限下根据马蒂厄特征函数计算得出的。我们还展示了半柔性聚合物与向列场相互作用的应用,并推导了强场中聚合物的向列序参量和平均伸长。

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