New signal processing method for the faster observation of natural-abundance 15N NMR spectra and its application to N5+. - Suppr | 超能文献

New signal processing method for the faster observation of natural-abundance 15N NMR spectra and its application to N5+.

作者信息

Kunikeev Sharif D, Taylor Howard S, Schroer Thorsten, Haiges Ralf, Bigler Jones C J, Christe Karl O

机构信息

Department of Chemistry and Loker Research Institute, University of Southern California, Los Angeles, 90089, USA.

出版信息

Inorg Chem. 2006 Jan 9;45(1):437-42. doi: 10.1021/ic051705a.

DOI:10.1021/ic051705a

Abstract

The new harmonic inversion noise reduction method was applied to (15)N natural-abundance NMR spectroscopy and N(5)SbF(6). This method is superior to conventional Fourier transform methods for processing FIDs and permits the detection of natural abundance (15)N NMR signals with significantly reduced numbers of scans and improved sensitivity. In addition to the confirmation of the previously reported chemical shifts for N(5)(+), the one bond coupling between N(beta) and N(gamma) could be observed for the first time. Its absolute value is compared to known coupling constants of other covalent azides and the free azide ion.

摘要

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