硫酸单酯和氨基磺酸酯的基态结构揭示了硫酰基和氨磺酰基转移相似的反应坐标。

Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer.

作者信息

Denehy Emma, White Jonathan M, Williams Spencer J

机构信息

School of Chemistry, University of Melbourne, Parkville, Australia.

出版信息

Chem Commun (Camb). 2006 Jan 21(3):314-6. doi: 10.1039/b513712h. Epub 2005 Nov 21.

DOI:10.1039/b513712h

PMID:16391745

Abstract

Structure/reactivity and structure/structure correlations of 5 sulfate monoesters and 11 sulfamate esters determined by low temperature X-ray crystallography reveal similar ground state deformations that suggest similar reaction coordinates for sulfuryl and sulfamyl group transfer.

摘要

通过低温X射线晶体学确定的5种硫酸单酯和11种氨基磺酸酯的结构/反应性以及结构/结构相关性揭示了相似的基态变形，这表明硫酰基和氨磺酰基转移具有相似的反应坐标。