Zhang Jihua, Kasala Kailash, Rewari Abhitej, Saravanamuttu Kalaichelvi
Department of Chemistry, McMaster University, Hamilton, Canada.
J Am Chem Soc. 2006 Jan 18;128(2):406-7. doi: 10.1021/ja056838+.
We report that a beam of spatially and temporally incoherent white light self-traps by initiating free-radical polymerization in an organosiloxane medium. Refractive index changes due to polymerization lead to the formation of a narrow channel waveguide that traps and guides the entire multimode, broadband beam without diffraction. The response time of the system, which is determined by the inherently slow rate of free-radical polymerization, exceeds by several orders of magnitude the femtosecond-scale random phase fluctuations that characterize white light. Self-trapping of incoherent light is possible in the photochemical medium because it responds to the time-averaged intensity profile of the white light beam.
我们报道了一束空间和时间上非相干的白光通过在有机硅氧烷介质中引发自由基聚合实现自陷。聚合导致的折射率变化会形成一个窄通道波导,该波导能捕获并引导整个多模宽带光束而无衍射现象。该系统的响应时间由自由基聚合固有的缓慢速率决定,比表征白光的飞秒级随机相位涨落超出几个数量级。在光化学介质中,非相干光的自陷是可能的,因为它对白光光束的时间平均强度分布有响应。