Havlík Tomás, Vidor e Souza Bruna, Bernardes Andrea Moura, Schneider Ivo André Homrich, Miskufová Andrea
Department of Non-Ferrous Metals and Waste Treatment, Faculty of Metallurgy, Technical University of Kosice, Letna 9, 042 00 Kosice, Slovak Republic.
J Hazard Mater. 2006 Jul 31;135(1-3):311-8. doi: 10.1016/j.jhazmat.2005.11.067. Epub 2006 Jan 25.
In this study, the hydrometallurgical processing of electric arc furnace (EAF) steelmaking dust is investigated on a laboratory scale under normal temperature and pressure conditions. The behaviour of zinc and iron under the influence of sulphuric acid as the leaching agent is discussed. The dependence between the temperature and acid concentration is investigated. The main aim is the transfer of zinc into the solution while iron ought to remain as a solid residue. The hydrometallurgical recovery of zinc from EAF dust is feasible with relatively high recovery yield, while iron mostly remains in the solid phase. It results from the use of sulphuric acid in low concentration. This way, it is possible to set up the conditions for the EAF dust leaching, adjusting sulphuric acid concentration in order to achieve an optimum zinc yield to the solution without iron dissolution. However, the problem is that the chemical and mineralogical composition of each steelmaking dust is individual.
在本研究中,在常温常压条件下,在实验室规模上对电弧炉(EAF)炼钢粉尘的湿法冶金工艺进行了研究。讨论了硫酸作为浸出剂时锌和铁的行为。研究了温度与酸浓度之间的关系。主要目的是将锌转移到溶液中,而铁应保留为固体残渣。从电弧炉粉尘中湿法冶金回收锌是可行的,回收率相对较高,而铁大多保留在固相中。这是由于使用了低浓度的硫酸。通过这种方式,可以为电弧炉粉尘浸出设定条件,调节硫酸浓度,以实现锌向溶液中的最佳回收率,同时不溶解铁。然而,问题在于每种炼钢粉尘的化学和矿物组成都是独特的。