在双功能Ni/Zr-β和Zr-β/Ni-MCM-41催化剂上香茅醛的多米诺环化和加氢制薄荷醇
Domino-cyclisation and hydrogenation of citronellal to menthol over bifunctional Ni/Zr-Beta and Zr-beta/Ni-MCM-41 catalysts.
作者信息
Nie Yuntong, Chuah Gaik-Khuan, Jaenicke Stephan
机构信息
Department of Chemistry, National University of Singapore, 3 Science Drive, Singapore117543.
出版信息
Chem Commun (Camb). 2006 Feb 21(7):790-2. doi: 10.1039/b513430g. Epub 2006 Jan 6.
DOI:10.1039/b513430g
PMID:16465342
Abstract
The one-pot conversion of (+/-)-citronellal to menthol can be selectively catalysed by either a bifunctional Ni/Zr-zeolite beta catalyst or a dual catalyst system of Zr-beta and Ni/MCM-41, giving a high diastereoselectivity to (+/-)-menthol of 90-94%.
摘要
（±）-香茅醛一锅法转化为薄荷醇可通过双功能Ni/Zr-β沸石催化剂或Zr-β与Ni/MCM-41的双催化剂体系进行选择性催化，对（±）-薄荷醇的非对映选择性高达90-94%。
Zotero 插件