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预应变对碳纳米管聚合物复合材料界面摩擦阻尼的影响。

Effect of pre-strain on interfacial friction damping in carbon nanotube polymer composites.

作者信息

Suhr J, Koratkar N

机构信息

Department of Mechanical, Aerospace and Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.

出版信息

J Nanosci Nanotechnol. 2006 Feb;6(2):483-6. doi: 10.1166/jnn.2006.096.

Abstract

This paper investigates the effect of mechanical pre-strain on interfacial friction damping in nanotube polymer composites. Oxidized single-walled carbon nanotubes were dispersed in a polycarbonate matrix using a solution mixing technique. To characterize the damping response, the material storage and loss modulus was measured by application of dynamic (sinusoidal) load to the nanocomposite in the uniaxial direction. A static pre-strain (in 0.35-0.85% range) was then superimposed on the dynamic strain to quantify its effect on the material response. The results indicate that application of pre-strain facilitates the activation of interfacial slip at the nanotube-polymer interfaces at relatively low dynamic strain amplitudes. This is because pre-strain raises the interfacial shear stress for the nanotube inclusions allowing the critical stress for tube-matrix interfacial slip to be reached at lower strain amplitudes. In this way pre-strain significantly improves the effectiveness of the nanotube-matrix sliding energy dissipation mechanism for damping enhancement in composite structures.

摘要

本文研究了机械预应变对纳米管聚合物复合材料界面摩擦阻尼的影响。采用溶液混合技术将氧化单壁碳纳米管分散在聚碳酸酯基体中。为了表征阻尼响应,通过在单轴方向对纳米复合材料施加动态(正弦)载荷来测量材料的储能模量和损耗模量。然后在动态应变上叠加静态预应变(范围为0.35 - 0.85%),以量化其对材料响应的影响。结果表明,预应变的施加有助于在相对较低的动态应变幅值下激活纳米管 - 聚合物界面处的界面滑移。这是因为预应变提高了纳米管夹杂物的界面剪切应力,使得在较低应变幅值下就能达到管 - 基体界面滑移的临界应力。通过这种方式,预应变显著提高了纳米管 - 基体滑动能量耗散机制在增强复合结构阻尼方面的有效性。

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