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单晶硫化镉树枝状晶体的软模板合成法

Soft-template synthesis of single-crystalline CdS dendrites.

作者信息

Niu Haixia, Yang Qing, Tang Kaibin, Xie Yi, Zhu Yongchun

机构信息

Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, Anhui 230026, PR China.

出版信息

J Nanosci Nanotechnol. 2006 Jan;6(1):162-7.

Abstract

The single-crystalline CdS dendrites have been fabricated from the reaction of CdCl2 and thiourea at 180 degrees C, in which glycine was employed as a soft template. The obtained products were explored by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and selected area electronic diffraction. The optical properties of CdS dendrites have been investigated by ultraviolet and visible light (UV-vis) and photoluminescence techniques. The investigations indicated that the dendrites were grown due to the anisotropic properties enhanced by the use of Glycine in the route.

摘要

通过氯化镉和硫脲在180℃下反应制备了单晶硫化镉树枝状晶体,其中甘氨酸用作软模板。通过X射线衍射、扫描电子显微镜、透射电子显微镜和选区电子衍射对所得产物进行了探究。利用紫外可见光谱(UV-vis)和光致发光技术研究了硫化镉树枝状晶体的光学性质。研究表明,由于在该合成路线中使用甘氨酸增强了各向异性,树枝状晶体得以生长。

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