Linus Pauling Institute of Science and Medicine, 440 Page Mill Road, Palo Alto, CA 94306.
Proc Natl Acad Sci U S A. 1985 Dec;82(24):8286-7. doi: 10.1073/pnas.82.24.8286.
The statistical resonating-valence-bond theory of metals is applied in the purely theoretical calculation of the composition of the Ni-Cu alloy at the foot of the curve of saturation ferromagnetic moment, which marks the boundary between hypoelectronic and hyperelectronic metals and determines the value of the number of metallic orbitals per atom. The results, Ni(44)Cu(56) and 0.722 metallic orbitals, agree with the observed values. This agreement provides strong support of the theory.
金属的统计共振价键理论被应用于纯理论计算 Ni-Cu 合金在饱和磁矩曲线的底部的组成,该曲线标志着低电子和高电子金属的边界,并决定了每个原子的金属轨道数。结果为 Ni(44)Cu(56)和 0.722 个金属轨道,与观察到的值一致。这种一致性为该理论提供了强有力的支持。