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CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.

作者信息

Lavallo Vincent, Canac Yves, Donnadieu Bruno, Schoeller Wolfgang W, Bertrand Guy

机构信息

UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.

出版信息

Angew Chem Int Ed Engl. 2006 May 19;45(21):3488-91. doi: 10.1002/anie.200600987.

Abstract
摘要

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The first century of ketenes (1905-2005): the birth of a versatile family of reactive intermediates.
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Molecules with exceptionally small HOMO-LUMO gaps.
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N-heterocyclic carbenes: reagents, not just ligands!
Angew Chem Int Ed Engl. 2004 Oct 4;43(39):5130-5. doi: 10.1002/anie.200301714.
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