一种具有五个由反式铂片段桥接的二茂铁封端臂的星形钌配合物。
A star-shaped ruthenium complex with five ferrocenyl-terminated arms bridged by trans-platinum fragments.
作者信息
Vives Guillaume, Carella Alexandre, Launay Jean-Pierre, Rapenne Gwénaël
机构信息
NanoSciences Group, Centre d'Elaboration de Matériaux et d'Etudes Structurales-CNRS, 29 rue Jeanne Marvig, BP 94347, F-31055, Toulouse Cedex 4, France.
出版信息
Chem Commun (Camb). 2006 Jun 4(21):2283-5. doi: 10.1039/b603508f. Epub 2006 Apr 28.
DOI:10.1039/b603508f
PMID:16718330
Abstract
We present the synthesis of the new heteropolytopic penta(4-ethynylphenyl)cyclopentadiene ligand, its complexation through the Cp ring to ruthenium tris(indazolyl)borate and through the terminal alkyne groups to five ferrocenyl ethynyl platinum units, yielding an undecanuclear heterotrimetallic complex.
摘要
我们展示了新型多齿五（4-乙炔基苯基）环戊二烯配体的合成，其通过环戊二烯基环与三（吲唑基）硼酸钌络合，并通过末端炔基与五个二茂铁乙炔基铂单元络合，生成一个十一核异三金属配合物。
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