非桥连半钛茂催化乙烯-降冰片烯共聚中降冰片烯（NBE）的显著掺入：NBE掺入与配位能之间更好的相关性。
Notable norbornene (NBE) incorporation in ethylene-NBE copolymerization catalysed by nonbridged half-titanocenes: better correlation between NBE incorporation and coordination energy.
作者信息
Nomura Kotohiro, Wang Wei, Fujiki Michiya, Liu Jingyu
机构信息
Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma, Nara 630-0101, Japan.
出版信息
Chem Commun (Camb). 2006 Jul 5(25):2659-61. doi: 10.1039/b605005k. Epub 2006 May 18.
DOI:10.1039/b605005k
PMID:16786078
Abstract
CpTiCl2(N=CtBu2) exhibits both remarkable catalytic activity and efficient norbornene (NBE) incorporation for ethylene-NBE copolymerization: the NBE incorporation by Cp'TiCl2(X) (X = N=CtBu2, O-2,6-iPr2C6H3; Cp' = Cp, C5Me5, indenyl) was related to the calculated coordination energy after ethylene insertion.
摘要
CpTiCl2(N=CtBu2)在乙烯-降冰片烯（NBE）共聚反应中表现出显著的催化活性和高效的降冰片烯（NBE）插入率：Cp'TiCl2(X)（X = N=CtBu2，O-2,6-iPr2C6H3；Cp' = Cp，C5Me5，茚基）的NBE插入率与乙烯插入后计算出的配位能有关。
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