聚[双[2-(1-环己烯基)乙基铵]二-μ-碘-二碘铅酸(II)]
Poly[bis[2-(1-cyclohexenyl)ethylammonium] di-mu-iodo-diodoplumbate(II)].
作者信息
Billing David G, Lemmerer Andreas
机构信息
School of Chemistry, University of the Witwatersrand, Private Bag 3, PO Wits 2050, South Africa.
出版信息
Acta Crystallogr C. 2006 Jul;62(Pt 7):m269-71. doi: 10.1107/S0108270106013953. Epub 2006 Jun 15.
The title compound, (C(8)H(16)N)(2)[PbI(4)], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2a(p) x 2a(p) superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI(6) octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl)ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.
标题化合物（C₈H₁₆N）₂[PbI₄]以无机 - 有机杂化钙钛矿形式结晶，采用不寻常的2a(p)×2a(p)超结构。因此，该结构在ab平面上由角共享的PbI₆八面体的二维片层组成，被2-(1-环己烯基)乙铵阳离子双层隔开。乙铵基团不在环己烯基环的平面内。
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