Suppr超能文献

[CuO/Cu2(OH)3Cl粉末的制备及其对染料光降解脱色的光谱行为研究]

[Study on preparation of CuO/Cu2 (OH)3Cl powder and its spectrum behavior for photodegradation decoloration of dyes].

作者信息

Deng Fan-Zheng, Zhu Ai-Xia, Yang Rui

机构信息

Department of Chemistry, Huaibei Coal Industrial Teachers' College, Huaibei 235000, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2006 Feb;26(2):299-301.

Abstract

Ultrafine powder CuO/Cu2 (OH)3Cl photocatalysts were prepared by CuCl2 and NaOH reaction and heating method of microwave liquid phase. XRD and FTIR were used to investigate the properties of the CuO/Cu2 (OH)3 Cl powder, and photocatalytic degradation of dyes by the CuO/Cu2 (OH)3 Cl catalysts was investigated. The results show that the decoloration rate is related to the pH value of dyes solution, irradiation time, as well as the intensity of irradiation. After irradiation with sun light for 4 h, the decoloration rate was up to 90% when the concentration of dyes was 20 mg x L(-1), the amount of catalyst was 40 mg) and the acidity was pH 8 in 50 mL dye solution. Adding Fe3+, H2O2 and other catalyst can improve the decoloration rate greatly. So the decoloration of dyes was due to photocatalytic degradation by analyzing the IR spectrum and the ultraviolet spectrum, and the photocatalytic activity of CuO/Cuz (OH)3 Cl powder is good in photocatalytic decoloration of dyes, such as amido black, indigo carmine and so on. The stability of photocatalytic nature of powder CuO/Cu2 (OH)3Cl was studied, and CuO/ Cu2 (OH)3 Cl powder can be recycled.

摘要

采用氯化铜与氢氧化钠反应结合微波液相加热法制备了超细粉末CuO/Cu2(OH)3Cl光催化剂。利用XRD和FTIR对CuO/Cu2(OH)3Cl粉末的性能进行了研究,并考察了CuO/Cu2(OH)3Cl催化剂对染料的光催化降解性能。结果表明,脱色率与染料溶液的pH值、辐照时间以及辐照强度有关。在50 mL染料溶液中,当染料浓度为20 mg·L(-1)、催化剂用量为40 mg且酸度为pH 8时,经太阳光照射4 h后,脱色率可达90%。添加Fe3+、H2O2等催化剂可大大提高脱色率。通过对红外光谱和紫外光谱的分析可知,染料的脱色是由于光催化降解作用,CuO/Cu2(OH)3Cl粉末在对酰胺黑、靛蓝胭脂红等染料的光催化脱色中具有良好的光催化活性。研究了CuO/Cu2(OH)3Cl粉末光催化性质的稳定性,该粉末可循环使用。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验