He Yan, Xu Jianming, Wang Haizhen, Wu Yuping
College of Environmental and Natural Resource Sciences, Zhejiang University, Hangzhou, China.
Environ Pollut. 2007 May;147(2):343-9. doi: 10.1016/j.envpol.2006.05.026. Epub 2006 Jul 7.
Dissipation of pentachlorophenol (PCP) in soil was investigated and the chemical relationships with soil properties were addressed. The results indicate that the dissipation of extractable PCP residues can be described using first-order kinetics equations, with a half-dissipation time (T(1/2)) ranging from 6.5 to 173.3d. The sharply different patterns of PCP dissipation in different soils were closely related to soil properties. Correlations of stepwise regression equations obtained were significant at 0.01 probability level between soil parameters and extractable PCP residues (R(2)=0.974**) as well as T(1/2) values (R(2)=0.882**). Using pH together with organic carbon content (OC) and soil particle size distribution, the dissipation dynamics of PCP in soil could be accurately predicted.
研究了五氯苯酚(PCP)在土壤中的消散情况,并探讨了其与土壤性质的化学关系。结果表明,可提取的PCP残留量的消散可用一级动力学方程描述,半衰期(T(1/2))为6.5至173.3天。不同土壤中PCP消散模式的显著差异与土壤性质密切相关。在0.01概率水平下,土壤参数与可提取的PCP残留量(R(2)=0.974**)以及T(1/2)值(R(2)=0.882**)之间逐步回归方程的相关性显著。结合土壤pH值、有机碳含量(OC)和土壤粒径分布,可以准确预测PCP在土壤中的消散动态。