文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期,新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

Complex behavior in coupled bromate oscillators.

作者信息

Chen Yu, Wang Jichang

机构信息

Department of Chemistry and Biochemistry, The University of Windsor, Windsor, ON N9B 3P4, Canada.

出版信息

J Phys Chem A. 2005 May 5;109(17):3950-6. doi: 10.1021/jp050756q.


DOI:10.1021/jp050756q
PMID:16833714
Abstract

In this study, coupled bromate-oscillators constructed by adding 1,4-cyclohexanedione (1,4-CHD) to the ferroin-catalyzed Belousov-Zhabotinsky reaction are investigated in a batch reactor under anaerobic conditions. Various complex behaviors such as sequential oscillations and bursting phenomena are observed. At low concentrations of ferroin or malonic acid (MA), the development of sequential oscillations is found to depend on the ratio of [1,4-CHD]/[ferroin] and [1,4-CHD]/[MA] rather than their absolute concentrations. As the concentration of MA or ferroin was increased gradually, however, the minimum 1,4-CHD concentration required to induce complex oscillations reaches a plateau. Perturbations by light illustrate that the first oscillatory window is governed by the ferroin-MA-BZ mechanism, whereas the 1,4-CHD-bromate oscillator plays a prominent role during the non-oscillatory evolution and the second oscillatory window. Our conclusion is further supported by numerical simulations in which sequential oscillations observed in experiments are qualitatively reproduced by a modified FKN mechanism.

摘要

相似文献

[1]
Complex behavior in coupled bromate oscillators.

J Phys Chem A. 2005-5-5

[2]
Coexistence of two bifurcation regimes in a closed ferroin-catalyzed Belousov-Zhabotinsky reaction.

J Phys Chem A. 2005-2-24

[3]
Collective reaction behavior of an oscillating system coupled with an excitable reaction.

J Chem Phys. 2006-6-21

[4]
Transient complex oscillations in a closed chemical system with coupled autocatalysis.

J Chem Phys. 2005-3-15

[5]
Chemical oscillations and waves in the catalyzed bromate-pyrocatechol reaction.

J Phys Chem A. 2008-5-8

[6]
Ferroin-induced complex oscillations in the bromate-hydroquinone photochemical reaction.

J Phys Chem A. 2009-6-4

[7]
Numerical investigation of photochemical behavior in bromate-1,4-cyclohexanedione reactions.

J Phys Chem A. 2009-2-5

[8]
Complex dynamics and enhanced photosensitivity in a modified Belousov-Zhabotinsky reaction.

J Chem Phys. 2008-6-28

[9]
A chemical oscillator based on the photoreduction of 2-methyl-1,4-benzoquinone.

J Phys Chem A. 2010-12-7

[10]
Uncatalyzed reactions in the classical Belousov-Zhabotinsky system. 2. The malonic acid-bromate reaction in acidic media.

J Phys Chem A. 2006-1-26

引用本文的文献

[1]
Towards Functional Droplet Architectures: a Belousov-Zhabotinsky Medium for Networks.

Sci Rep. 2018-8-23

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索