Ağdağ Osman Nuri, Sponza Delia Teresa
Pamukkale University, Engineering Faculty, Environmental Engineering Department, Kinikli Campus, Denizli, Turkey.
J Hazard Mater. 2007 Feb 9;140(1-2):75-85. doi: 10.1016/j.jhazmat.2006.06.059. Epub 2006 Jun 29.
In this study, the feasibility of the anaerobic co-digestion of a mixed industrial sludge with municipal solid wastes (MSW) was investigated in three simulated anaerobic landfilling bioreactors during a 150-day period. All of the reactors were operated with leachate recirculation. One of them was loaded only with MSW (control reactor); the second reactor was loaded with mixed industrial sludge and MSW, the weight ratio of the MSW to mixed industrial sludge was 1:1 (based on dry solid) (Run 1); the third reactor was loaded with mixed industrial sludge and MSW, the weight ratio of the MSW to mixed industrial sludge was 1:2 (based on dry solid) (Run 2). The VFA concentrations decreased significantly in Run 1 and Run 2 reactors at the end of 150 days. The pH values were higher in Run 1 and Run 2 reactors compared to control reactor. The differences between leachate characteristics, the biodegradation and the bioefficiency of the reactors were compared. The NH(4)-N concentrations released to leachate from mixed sludge in Run 1 and Run 2 reactors were lower than that of control reactor. The BOD(5)/COD ratios in Run 1 and Run 2 reactors were lower than that of control reactor at the end of 150 days. Cumulative methane gas productions and methane percentages were higher in Run 1 and Run 2 reactors. Reductions in waste quantity, carbon percentage and settlement of the waste were better in Run 1 and Run 2 reactors compared to control reactor at the end of 150 days. Furthermore, TN and TP removals in waste were higher in reactors containing industrial sludge compared to control. The toxicity test results showed that toxicity was observed in reactors containing industrial mixed sludge.
在本研究中,在三个模拟厌氧填埋生物反应器中,对混合工业污泥与城市固体废物(MSW)进行厌氧共消化的可行性进行了为期150天的研究。所有反应器均采用渗滤液回流操作。其中一个仅装填城市固体废物(对照反应器);第二个反应器装填混合工业污泥和城市固体废物,城市固体废物与混合工业污泥的重量比为1:1(基于干固体)(运行1);第三个反应器装填混合工业污泥和城市固体废物,城市固体废物与混合工业污泥的重量比为1:2(基于干固体)(运行2)。在150天结束时,运行1和运行2反应器中的挥发性脂肪酸(VFA)浓度显著降低。与对照反应器相比,运行1和运行2反应器中的pH值更高。比较了各反应器渗滤液特性、生物降解和生物效率之间的差异。运行1和运行2反应器中混合污泥释放到渗滤液中的NH₄-N浓度低于对照反应器。在150天结束时,运行1和运行2反应器中的BOD₅/COD比值低于对照反应器。运行1和运行2反应器中的累计甲烷气体产量和甲烷百分比更高。在150天结束时,与对照反应器相比,运行1和运行2反应器中废物量的减少、碳百分比和废物沉降情况更好。此外,与对照相比,含有工业污泥的反应器中废物中总氮(TN)和总磷(TP)的去除率更高。毒性测试结果表明,在含有工业混合污泥的反应器中观察到了毒性。