He Yun
School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062, People's Republic of China.
Acta Crystallogr C. 2006 Oct;62(Pt 10):m469-71. doi: 10.1107/S0108270106034536. Epub 2006 Sep 12.
In the title compound, [Ni(C15H8O7S)(H2O)4].C3H7NO.H2O, the NiII cation is chelated by a 7-hydroxy-5-oxidoflavone-6-sulfonate ligand through one oxide and one carbonyl O atom, and the sixfold coordination is completed by four aqua ligands. Individual molecules are linked into hydrogen-bonded dimers by way of five pairs of O-H...O hydrogen bonds. These dimers, in turn, determine a three-dimensional supramolecular arrangement through a variety of interdimeric interactions, such as O-H...O, C-H...O and pi-pi stacking.
在标题化合物[Ni(C₁₅H₈O₇S)(H₂O)₄].C₃H₇NO.H₂O中,NiII阳离子通过一个氧化物和一个羰基O原子与7-羟基-5-氧化黄酮-6-磺酸盐配体螯合,通过四个水配体完成六配位。单个分子通过五对O-H...O氢键连接成氢键二聚体。这些二聚体又通过各种二聚体间相互作用,如O-H...O、C-H...O和π-π堆积,确定三维超分子排列。