Photodissociation of methane: exploring potential energy surfaces.

The potential energy surface for the first excited singlet state (S(1)) of methane is explored using multireference singles and doubles configuration interaction calculations, employing a valence triple zeta basis set. A larger valence quadruple zeta basis is used to calculate the vertical excitation energy and dissociation energies. All stationary points found on the S(1) surface are saddle points and have imaginary frequencies for symmetry-breaking vibrations. By studying several two-dimensional cuts through the potential energy surfaces, it is argued that CH(4) in the S(1) state will distort to planar structures. Several conical intersection seams between the ground state surface S(0) and the S(1) surface have been identified at planar geometries. The conical intersections provide electronically nonadiabatic pathways towards products CH(3)((approximately)X (2)A"(2))+H, CH(2)((approximately)a (1)A(1))+H(2), or CH(2)((approximately)X (3)B(1))+H+H. The present results thereby make it plausible that the CH(3)((approximately)X (2)A"(2))+H and CH(2)((approximately)a (1)A(1))+H(2) channels are major dissociation channels, as has been observed experimentally.