文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期,新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

贝洛索夫-扎博廷斯基反应的受控激发:实验步骤。

Controlled excitations of the Belousov-Zhabotinsky reaction: Experimental procedures.

作者信息

Peralta Catalina, Frank Claudia, Zaharakis Alex, Cammalleri Carolyn, Testa Matthew, Chaterpaul Stephen, Hilaire Christian, Lang Daniel, Ravinovitch Daniel, Sobel Sabrina G, Hastings Harold M

机构信息

Department of Chemistry, Hofstra University, Hempstead, New York 11549-1510, USA.

出版信息

J Phys Chem A. 2006 Nov 9;110(44):12145-9. doi: 10.1021/jp062512r.


DOI:10.1021/jp062512r
PMID:17078609
Abstract

The purpose of this research was to explore the unstirred, ferroin-catalyzed Belousov-Zhabotinsky (BZ) reaction as an experimental model for the response of excitable media to small perturbations (slightly larger than the threshold for excitations). Following Showalter et al. (Showalter, K.; Noyes, R. M.; Turner, H. J.Am. Chem. Soc. 1979, 101, 7463-69), we used a positively biased silver electrode to release silver ions into a BZ reaction mixture, removing bromide ions and causing an excitation if sufficient bromide was removed. We found (1) a scaling region in which the delay before activation increased linearly as the size of the perturbation decreased, qualitatively consistent with but not fully explained by the Oregonator of Field et al. (Field, R. J.; Körõs, E.; Noyes, R. M. J. Am. Chem. Soc. 1972, 94, 8649-64); (2) evidence for a 10 s oligomerization time scale; and (3) that activations were always delayed until after the end of a pulse of current, with the delay essentially constant for sufficiently long pulses, an effect not seen in simple ODE models but consistent with the anomalously large current apparently required for activation (Showalter, K.; Noyes, R. M. J. Am. Chem. Soc. 1976, 98, 3730-31) and explainable by bromide transport. Overall, the BZ system appeared to be well-suited as an experimental prototype, despite its complexity.

摘要

本研究的目的是探索未搅拌的、亚铁离子催化的贝洛索夫-扎博京斯基(BZ)反应,作为可兴奋介质对小扰动(略大于激发阈值)响应的实验模型。遵循绍沃尔特等人(绍沃尔特,K.;诺伊斯,R. M.;特纳,H. J.《美国化学会志》1979年,101卷,7463 - 69页)的方法,我们使用带正电的银电极将银离子释放到BZ反应混合物中,去除溴离子,若去除的溴离子足够,则引发一次激发。我们发现:(1)一个标度区域,其中激活前的延迟随着扰动大小减小而线性增加,定性上与菲尔德等人的俄勒冈模型(菲尔德,R. J.;科罗斯,E.;诺伊斯,R. M.《美国化学会志》1972年,94卷,8649 - 64页)一致,但未得到该模型的充分解释;(2)有证据表明存在一个10秒的寡聚时间尺度;(3)激活总是延迟到电流脉冲结束之后,对于足够长的脉冲,延迟基本恒定,这种效应在简单的常微分方程模型中未见到,但与激活显然所需的异常大电流(绍沃尔特,K.;诺伊斯,R. M.《美国化学会志》1976年,98卷,3730 - 31页)一致,并且可以用溴离子传输来解释。总体而言,尽管BZ系统很复杂,但它似乎非常适合作为一个实验原型。

相似文献

[1]
Controlled excitations of the Belousov-Zhabotinsky reaction: Experimental procedures.

J Phys Chem A. 2006-11-9

[2]
Coexistence of two bifurcation regimes in a closed ferroin-catalyzed Belousov-Zhabotinsky reaction.

J Phys Chem A. 2005-2-24

[3]
Bromide control, bifurcation and activation in the Belousov-Zhabotinsky reaction.

J Phys Chem A. 2008-5-29

[4]
Oxidation state of BZ reaction mixtures.

J Phys Chem A. 2006-1-12

[5]
The Influence of a gradient static magnetic field on an unstirred Belousov-Zhabotinsky reaction.

Bioelectromagnetics. 2008-12

[6]
Oregonator Scaling Motivated by the Showalter-Noyes Limit.

J Phys Chem A. 2016-10-20

[7]
Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions.

Phys Chem Chem Phys. 2008-11-28

[8]
Response of a chemical wave to local pulse irradiation in the ruthenium-catalyzed Belousov-Zhabotinsky reaction.

Phys Chem Chem Phys. 2015-4-14

[9]
Science, serendipity, coincidence, and the Oregonator at the University of Oregon, 1969-1974.

Chaos. 2022-5

[10]
Chemical wave propagation preserved on an inhibitory field in the ruthenium-catalyzed Belousov-Zhabotinsky reaction.

J Phys Chem A. 2013-10-3

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索