Wei Li-hong, Jiang Xiu-min, Li Ai-min
School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China.
Huan Jing Ke Xue. 2006 Sep;27(9):1722-6.
Three species micro-pulverized coals(Hegang, Tiefa, Zhungeer coal) were studied, the mineral matters (MgO, CaO, Al2O3 and Fe3O4) were respectively added to the coals. The combustion of samples were studied to investigate the effect of mineral matter on transformation of sulfur during combustion by the combined of DTG and GC-MS, the flowmeter 50 mL/min, heating rate 20 degrees C/ min, oxygen volume percentage 20% . The SO2 release curve of primitive micro-pulverized coal appear three peaks during the combustion, but the demineralized sample appear two peaks. The species of coal has effect on temperature of the maximum release rate of SOz, the release rate of SO2 of Hegang coal is even in three temperature ranges, Tiefa coal appear maximum value about 500 degrees C and Zhungeer coal about 200 degrees C which probably due to the different amount of all kinds of sulfur in primitive coal sample. The mineral matter (MgO, CaO, Al2O3 and Fe3O4) have sulfur retention and catalyzing effect on SO2 the combustion of coal. The amount and species of mineral matter and species of coal determine the sulfur retention effect.
研究了三种超细煤粉(鹤岗煤、铁法煤、准格尔煤),并分别向这些煤中添加了矿物质(MgO、CaO、Al2O3和Fe3O4)。通过DTG和GC-MS联用,在流量计50 mL/min、升温速率20℃/min、氧气含量体积百分比20%的条件下,对样品燃烧进行研究,以考察矿物质对燃烧过程中硫转化的影响。原始超细煤粉的SO2释放曲线在燃烧过程中出现三个峰值,但脱矿物质样品出现两个峰值。煤种对SO2最大释放速率的温度有影响,鹤岗煤的SO2释放速率在三个温度范围内较为均匀,铁法煤在约500℃出现最大值,准格尔煤在约200℃出现最大值,这可能是由于原始煤样中各种硫的含量不同。矿物质(MgO、CaO、Al2O3和Fe3O4)对煤燃烧过程中的SO2有固硫和催化作用。矿物质的含量和种类以及煤种决定了固硫效果。