Ding Zhen, Feng Xiao-gang, Chen Xiao-dong, Fu De-gang, Yuan Chun-wei
Jiangsu Center for Diseases Prevention and Control, Nanjing 210009, China.
Huan Jing Ke Xue. 2006 Sep;27(9):1814-9.
Three different metal ions doped TiO2 photocatalysts, which were prepared by the sol-gel method, were immobilized to porous nickel mesh by coating. The photocatalytic degradation activity of the supported photocatalyst on formaldehyde and volatile organic compounds (VOCs) was investigated. The results show that the nanometer TiO2 has an anatase structure. The photocatalytic degradation rate of formaldehyde and VOCs of 1.5% La3+ doped TiO2 coated on porous nickel mesh at 90 min are: 94% and 87%, higher than undoped TiO2: 83% and 72%, Fe3+ doped TiO2: 62% and 62%, Ag+ doped TiO2: 86% [Chinese character: see text] 81%. The orders of photocatalytic degradation rate on formaldehyde and VOCs with different content of La3+ doped TiO2 are as follows: 1.5% > 1% > 2% > undoped, 1.5% is the optimum La3+ doped content. Decreasing circular wind speed and using 254 nm or 365 nm ultraviolet wavelength will not influence the photocatalytic degradation rate of formaldehyde and VOCs.
通过溶胶-凝胶法制备的三种不同金属离子掺杂的TiO₂光催化剂,通过涂层固定在多孔镍网上。研究了负载型光催化剂对甲醛和挥发性有机化合物(VOCs)的光催化降解活性。结果表明,纳米TiO₂具有锐钛矿结构。90分钟时,负载在多孔镍网上的1.5%La³⁺掺杂TiO₂对甲醛和VOCs的光催化降解率分别为:94%和87%,高于未掺杂TiO₂的83%和72%、Fe³⁺掺杂TiO₂的62%和62%、Ag⁺掺杂TiO₂的86%[汉字:见原文]81%。不同La³⁺掺杂量的TiO₂对甲醛和VOCs的光催化降解率顺序如下:1.5%>1%>2%>未掺杂,1.5%是最佳La³⁺掺杂量。降低循环风速以及使用254nm或365nm紫外波长不会影响甲醛和VOCs的光催化降解率。