Huang Su-Chen, Chang Fang-Chih, Lo Shang-Lien, Lee Ming-Yu, Wang Chu-Fang, Lin Jyh-Dong
Department of Atomic Science, National Tsing Hua University, 101, Sec. 2, Kuang Fu Road, Hsinchu 300, Taiwan, ROC.
J Hazard Mater. 2007 Jun 1;144(1-2):52-8. doi: 10.1016/j.jhazmat.2006.09.094. Epub 2006 Oct 11.
In this study, artificial lightweight aggregate (LWA) manufactured from recycled resources was investigated. Residues from mining, fly ash from an incinerator and heavy metal sludge from an electronic waste water plant were mixed into raw aggregate pellets and fed into a tunnel kiln to be sintered and finally cooled rapidly. Various feeding and sintering temperatures were employed to examine their impact on the extent of vitrification on the aggregate surface. Microstructural analysis and toxicity characteristic leaching procedure (TCLP) were also performed. The results show that the optimum condition of LWA fabrication is sintering at 1150 degrees C for 15 min with raw aggregate pellets fed at 750 degrees C. The rapidly vitrified surface envelops the gas produced with the increase in internal temperature and cooling by spraying water prevents the aggregates from binding together, thus forming LWA with specific gravity of 0.6. LWA produced by sintering in tunnel kiln shows good vitrified surface, low water absorption rate below 5%, and low cylindrical compressive strength of 4.3 MPa. In addition, only trace amounts of heavy metals were detected, making the LWA non-hazardous for construction use.
在本研究中,对由回收资源制造的人造轻骨料(LWA)进行了研究。将采矿残渣、焚烧炉飞灰和电子废水处理厂的重金属污泥混入生骨料球团中,送入隧道窑进行烧结,最后快速冷却。采用不同的进料温度和烧结温度,以考察它们对骨料表面玻璃化程度的影响。还进行了微观结构分析和毒性特性浸出程序(TCLP)。结果表明,LWA制备的最佳条件是在1150℃下烧结15分钟,生骨料球团在750℃下进料。快速玻璃化的表面包裹着随着内部温度升高而产生的气体,喷水冷却可防止骨料粘结在一起,从而形成比重为0.6的LWA。在隧道窑中烧结生产的LWA具有良好的玻璃化表面,吸水率低于5%,圆柱抗压强度低,为4.3MPa。此外,仅检测到痕量重金属,使得该LWA用于建筑用途时无危害。