Suppr超能文献

聚合物薄膜的去湿

Dewetting of thin polymer films.

作者信息

Vilmin T, Raphaël E

机构信息

Laboratoire de Physico-Chimie Théorique, UMR CNRS 7083, ESPCI, 10 rue Vauquelin, 75231, Paris Cedex 05, France.

出版信息

Eur Phys J E Soft Matter. 2006 Oct;21(2):161-74. doi: 10.1140/epje/i2006-10057-5. Epub 2006 Dec 5.

Abstract

We study the dewetting of thin polymer films deposited on slippery substrate. Recent experiments on these systems have revealed many unexpected features. We develop here a model that takes into account the rheological properties of polymer melts, focussing on two dewetting geometries (the receding of a straight edge, and the opening of a hole). We show that the friction law associated with the slippage between the film and the substrate has a direct influence on the dewetting dynamic. In addition, we demonstrate that residual stresses, which can be stored in the films due to their viscoelasticity, are a source of destabilization for polymer films, and accelerate the dewetting process.

摘要

我们研究了沉积在光滑基底上的聚合物薄膜的去湿现象。近期对这些体系的实验揭示了许多意想不到的特征。我们在此开发了一个考虑聚合物熔体流变特性的模型,重点关注两种去湿几何形状(直边的后退和孔洞的张开)。我们表明,与薄膜和基底之间滑动相关的摩擦定律对去湿动力学有直接影响。此外,我们证明,由于薄膜的粘弹性而可能存储在其中的残余应力是聚合物薄膜失稳的一个来源,并加速了去湿过程。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验