利用八面体金属离子和一种柔性分子夹构建三角棱柱和四方棱柱笼状结构。
Assembly of trigonal and tetragonal prismatic cages from octahedral metal ions and a flexible molecular clip.
作者信息
Liu Zhi-Min, Liu Yu, Zheng Sheng-Run, Yu Zhi-Quan, Pan Mei, Su Cheng-Yong
机构信息
MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
出版信息
Inorg Chem. 2007 Jul 23;46(15):5814-6. doi: 10.1021/ic062270+. Epub 2007 Jan 26.
PMID:17256851
Abstract
Reaction of a semirigid ligand with two octahedral metal ions with restricted coordination symmetry afforded metalated container complexes showing trigonal or tetragonal outer shapes and inner cavities.
摘要
一个具有受限配位对称性的半刚性配体与两个八面体金属离子反应，得到了呈现三角或四方外形及内腔的金属化容器配合物。
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