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通过喷雾热解方法合成具有巨大矫顽力的碳包覆磁性纳米粒子。

Synthesis of carbon encapsulated magnetic nanoparticles with giant coercivity by a spray pyrolysis approach.

作者信息

Wang Jian Nong, Zhang Li, Yu Fan, Sheng Zhao Ming

机构信息

School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200030, People's Republic of China.

出版信息

J Phys Chem B. 2007 Mar 1;111(8):2119-24. doi: 10.1021/jp0674118. Epub 2007 Feb 2.

Abstract

Carbon encapsulated magnetic (metal) nanoparticles (CEMNPs) have wide applications in biomedicine and the magnetic recording industry. However, synthesis of such particles with a high coercive force and good ferromagnetism is still a great challenge. The present study reports a new method for the continuous production of CEMNPs of high purity. This involves the spray pyrolysis of a mixture of iron pentacarbonyl and ethanol at 500-900 degrees C. Results show that the Fe (or Fe3C) particles synthesized at 700 and 900 degrees C were well encapsulated by graphitic layers with rare byproducts such as carbon nanotubes, nanofibers, or bulk amorphous carbon. Those synthesized at 700 degrees C had a particle size of 30-50 nm, a giant coercive force of 867 Oe, and a good magnetic remanence of 33% at room temperature. The present approach based on spray pyrolysis is advantageous over previous ones in suitability for large-scale production, and the synthesized material has wide applications in many fields.

摘要

碳包覆磁性(金属)纳米颗粒(CEMNPs)在生物医学和磁记录行业有广泛应用。然而,合成具有高矫顽力和良好铁磁性的此类颗粒仍然是一个巨大挑战。本研究报告了一种连续生产高纯度CEMNPs的新方法。这涉及在500 - 900摄氏度下对五羰基铁和乙醇的混合物进行喷雾热解。结果表明,在700和900摄氏度合成的Fe(或Fe3C)颗粒被石墨层良好包覆,副产物如碳纳米管、纳米纤维或块状非晶碳很少。在700摄氏度合成的颗粒粒径为30 - 50纳米,室温下具有867奥斯特的巨大矫顽力和33%的良好剩磁。基于喷雾热解的本方法在适合大规模生产方面优于先前方法,且合成材料在许多领域有广泛应用。

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