Wang Jian Nong, Zhang Li, Yu Fan, Sheng Zhao Ming
School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200030, People's Republic of China.
J Phys Chem B. 2007 Mar 1;111(8):2119-24. doi: 10.1021/jp0674118. Epub 2007 Feb 2.
Carbon encapsulated magnetic (metal) nanoparticles (CEMNPs) have wide applications in biomedicine and the magnetic recording industry. However, synthesis of such particles with a high coercive force and good ferromagnetism is still a great challenge. The present study reports a new method for the continuous production of CEMNPs of high purity. This involves the spray pyrolysis of a mixture of iron pentacarbonyl and ethanol at 500-900 degrees C. Results show that the Fe (or Fe3C) particles synthesized at 700 and 900 degrees C were well encapsulated by graphitic layers with rare byproducts such as carbon nanotubes, nanofibers, or bulk amorphous carbon. Those synthesized at 700 degrees C had a particle size of 30-50 nm, a giant coercive force of 867 Oe, and a good magnetic remanence of 33% at room temperature. The present approach based on spray pyrolysis is advantageous over previous ones in suitability for large-scale production, and the synthesized material has wide applications in many fields.
碳包覆磁性(金属)纳米颗粒(CEMNPs)在生物医学和磁记录行业有广泛应用。然而,合成具有高矫顽力和良好铁磁性的此类颗粒仍然是一个巨大挑战。本研究报告了一种连续生产高纯度CEMNPs的新方法。这涉及在500 - 900摄氏度下对五羰基铁和乙醇的混合物进行喷雾热解。结果表明,在700和900摄氏度合成的Fe(或Fe3C)颗粒被石墨层良好包覆,副产物如碳纳米管、纳米纤维或块状非晶碳很少。在700摄氏度合成的颗粒粒径为30 - 50纳米,室温下具有867奥斯特的巨大矫顽力和33%的良好剩磁。基于喷雾热解的本方法在适合大规模生产方面优于先前方法,且合成材料在许多领域有广泛应用。