Alexander G P, Yeomans J M
Rudolf Peierls Centre for Theoretical Physics, University of Oxford, 1 Keble Road, Oxford, OX1 3NP, United Kingdom.
Phys Rev E Stat Nonlin Soft Matter Phys. 2006 Dec;74(6 Pt 1):061706. doi: 10.1103/PhysRevE.74.061706. Epub 2006 Dec 27.
We present an investigation of the phase diagram of cholesteric liquid crystals within the framework of Landau-de Gennes theory. The free energy is modified to incorporate all three Frank elastic constants and to allow for a temperature dependent pitch in the cholesteric phase. It is found that the region of stability of the cubic blue phases depends significantly on the value of the elastic constants, being reduced when the bend elastic constant is larger than splay and when twist is smaller than the other two. Most dramatically we find a large increase in the region of stability of blue phase I, and a qualitative change in the phase diagram, in a system where the cholesteric phase displays helix inversion.
我们在朗道 - 德热纳理论框架内对胆甾相液晶的相图进行了研究。自由能经过修正,纳入了所有三个弗兰克弹性常数,并考虑了胆甾相中介于温度的螺距。结果发现,立方蓝相的稳定区域显著取决于弹性常数的值,当弯曲弹性常数大于展曲弹性常数且扭曲弹性常数小于其他两个弹性常数时,该稳定区域会减小。最引人注目的是,在胆甾相呈现螺旋反转的系统中,我们发现蓝相I的稳定区域大幅增加,且相图发生了质的变化。