Zhang Yunyan, Mu Jin
Department of Chemistry, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, People's Republic of China.
J Colloid Interface Sci. 2007 May 15;309(2):478-84. doi: 10.1016/j.jcis.2007.01.011. Epub 2007 Feb 9.
One-pot synthesis of Ag/ZnO composites is described by a simple hydrothermal approach. In the reaction process, hexamethylenetetramine (HMT) can convert into ammonia and formaldehyde, which are used as a precipitant for the fabrication of ZnO and a reducing agent for the loading of metal Ag, respectively. The UV emission of ZnO is obviously enhanced by the deposition of silver islands on its surface. The photocatalytic characterization reveals that the composites behave high photocatalytic activity for a solution of rhodamine B. The influence of Ag+ ions on the morphology of ZnO is discussed. The composites are characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL).
通过一种简单的水热法描述了一锅法合成Ag/ZnO复合材料。在反应过程中,六亚甲基四胺(HMT)可转化为氨和甲醛,它们分别用作制备ZnO的沉淀剂和负载金属Ag的还原剂。银岛沉积在ZnO表面显著增强了其紫外发射。光催化表征表明,该复合材料对罗丹明B溶液具有高光催化活性。讨论了Ag+离子对ZnO形貌的影响。通过粉末X射线衍射(XRD)、扫描电子显微镜(SEM)和光致发光(PL)对复合材料进行了表征。