Kwiatkowski Mirosław
Faculty of Fuels and Energy, AGH-University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow, Poland.
Langmuir. 2007 Feb 27;23(5):2569-81. doi: 10.1021/la062835e.
The paper presents a properties study of the new LBET class models for heterogeneous multilayer adsorption and its applicability to analysis of microporous carbonaceous adsorbents in comparison to the selected classical equations. This paper shows that the LBET formulas give a good insight into the pore size distribution and dominant pore shape. Moreover, they provide more reliable evaluation of material surface area than the popular classical equations. This research constitutes a significant development and completion of the author's earlier works and provides a basis for the evaluation of reliability of parameters calculated for real systems.
本文介绍了用于多相多层吸附的新型LBET类模型的性能研究,以及与所选经典方程相比,其在微孔碳质吸附剂分析中的适用性。本文表明,LBET公式能很好地洞察孔径分布和主要孔形状。此外,与流行的经典方程相比,它们能提供更可靠的材料表面积评估。这项研究是作者早期工作的重大发展和完善,为评估实际系统计算参数的可靠性提供了依据。