Wu Lan, Liu Mingzhu
Department of Chemistry and State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Bioresour Technol. 2008 Feb;99(3):547-54. doi: 10.1016/j.biortech.2006.12.027. Epub 2007 Feb 22.
A double-coated slow-release NPK compound fertilizer with superabsorbent and water-retention was prepared by crosslinked poly(acrylic acid)/diatomite - containing urea (the outer coating), chitosan (the inner coating), and water-soluble granular fertilizer NPK (the core). The effects of the amount of crosslinker, initiator, degree of neutralization of acrylic acid, initial monomer and diatomite concentration on water absorbency were investigated and optimized. The water absorbency of the product was 75 times its own weight if it was allowed to swell in tap water at room temperature for 2 h. Atomic absorption spectrophotometer and element analysis results showed that the product contained 8.47% potassium (shown by K(2)O), 8.51% phosphorus (shown by P(2)O(5)), and 15.77% nitrogen. We also investigated the water-retention property of the product and the slow release behavior of N, P and K in the product. This product with excellent slow release and water-retention capacity, being nontoxic in soil and environment-friendly, could be especially useful in agricultural and horticultural applications.
一种具有超强吸水保水性能的双层缓释氮磷钾复合肥,由交联聚丙烯酸/含尿素的硅藻土(外层包膜)、壳聚糖(内层包膜)和水溶性颗粒肥料氮磷钾(核心)制备而成。研究并优化了交联剂用量、引发剂用量、丙烯酸中和度、初始单体及硅藻土浓度对吸水率的影响。该产品在室温下于自来水中溶胀2小时后,吸水率可达自身重量的75倍。原子吸收分光光度计和元素分析结果表明,该产品含钾8.47%(以K₂O计)、含磷8.51%(以P₂O₅计)、含氮15.77%。我们还研究了该产品的保水性能以及产品中氮、磷、钾的缓释行为。该产品具有优异的缓释和保水能力,在土壤中无毒且环境友好,尤其适用于农业和园艺应用。