基于三蝶烯的柱状大环聚醚与双季铵盐的络合作用：离子控制的客体结合与释放
Complexation of triptycene-based cylindrical macrotricyclic polyether toward diquaternary salts: ion-controlled binding and release of the guests.
作者信息
Han Tao, Zong Qian-Shou, Chen Chuan-Feng
机构信息
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
出版信息
J Org Chem. 2007 Apr 13;72(8):3108-11. doi: 10.1021/jo070035i. Epub 2007 Mar 15.
PMID:17358081
Abstract
Triptycene-based cylindrical macrotricyclic polyether 1 has been proved to be an efficient host for the complexation with diquaternary salts in solution and in the solid state. Moreover, it was also found that binding and release of the guest molecules could be easily controlled by the addition and removal of potassium ions.
摘要
基于三蝶烯的圆柱形大环三环聚醚1已被证明是一种在溶液和固态中与双季铵盐络合的有效主体。此外，还发现通过添加和去除钾离子可以轻松控制客体分子的结合和释放。
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