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采用紫外吸收检测的毛细管电泳法测定聚合物介质中的苄基三乙基氯化铵。

Determination of benzyltriethyl ammonium chloride from polymeric media by capillary electrophoresis with ultraviolet absorbance detection.

作者信息

Lin Weisheng, Shi Haiying, May Trisha, Shi Honglan, Ma Yinfa

机构信息

Department of Chemistry and Environmental Research Center, University of Missouri-Rolla, 1870 Miner Circle, Rolla, MO 65409, United States.

出版信息

Anal Chim Acta. 2007 Jan 30;583(1):98-102. doi: 10.1016/j.aca.2006.09.059. Epub 2006 Oct 5.

Abstract

The importance of benzyltriethyl ammonium chloride (BTEAC) in industrial applications has stimulated the development of a number of methods for its determination. In this paper, a high performance capillary electrophoresis (CE) method, coupled with an extraction technique for determining BTEAC in organic matrices, was developed. BTEAC was extracted from organic samples with a 20 mM sodium phosphate solution. Sonication was used to improve extraction efficiency. The repeatability and recovery of the technique have been studied and it was proven that the technique is satisfactory for quantitative determination of BTEAC in organic matrices. Separation was achieved within 6 min in 20 mM sodium phosphate buffer at pH 5.0. The recovery was above 92%. The detection limit for BTEAC is 5 mg L(-1) with a signal-to-noise ratio of 3. The linear range of the technique is 5-100 mg L(-1). This method is simple, fast, low-cost, and can be easily used for product quality control in industrial laboratories.

摘要

苄基三乙基氯化铵(BTEAC)在工业应用中的重要性推动了多种测定方法的发展。本文开发了一种高效毛细管电泳(CE)方法,并结合萃取技术用于测定有机基质中的BTEAC。用20 mM磷酸钠溶液从有机样品中萃取BTEAC。采用超声处理提高萃取效率。研究了该技术的重复性和回收率,结果表明该技术对于定量测定有机基质中的BTEAC是令人满意的。在pH 5.0的20 mM磷酸钠缓冲液中,6分钟内实现分离。回收率高于92%。BTEAC的检测限为5 mg L(-1),信噪比为3。该技术的线性范围为5 - 100 mg L(-1)。此方法简单、快速、成本低,可轻松用于工业实验室的产品质量控制。

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