Bánsági Tamás, Palczewski Christine, Steinbock Oliver
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, USA.
J Phys Chem A. 2007 Apr 5;111(13):2492-7. doi: 10.1021/jp068425g. Epub 2007 Mar 3.
Experiments with the 1,4-cyclohexanedione Belousov-Zhabotinsky reaction demonstrate that three-dimensional scroll waves can rotate around filaments that end in the wake of a traveling excitation pulse. The vortex structures nucleate during the collision of three nonrotating excitation pulses. The nucleation process and the wave-termination of filaments are direct consequences of the system's anomalous dispersion relation. Vortex filaments are found to expand with about twice the speed of their anchoring wave fronts. Filament expansion is accompanied by the build-up of phase differences in spiral rotation creating strongly twisted wave structures. Experiments employ optical tomography for the reconstruction of the three-dimensional wave patterns.
对1,4 - 环己二酮贝洛索夫 - 扎博廷斯基反应进行的实验表明,三维螺旋波可以围绕在行进的激发脉冲尾迹中终止的细丝旋转。涡旋结构在三个非旋转激发脉冲碰撞时形成。细丝的成核过程和波终止是系统异常色散关系的直接结果。发现涡旋细丝以其锚定波前速度的两倍左右扩展。细丝扩展伴随着螺旋旋转中相位差的积累,形成强烈扭曲的波结构。实验采用光学层析成像来重建三维波模式。