Valley David T, Rice Stuart A, Cui Bianxiao, Ho Hau My, Diamant Haim, Lin Binhua
Department of Chemistry, The James Franck Institute, The University of Chicago, Chicago, Illinois 60637, USA.
J Chem Phys. 2007 Apr 7;126(13):134908. doi: 10.1063/1.2719191.
The authors report the results of measurements of the center of mass and relative pair diffusion coefficients in quasi-one-dimensional (q1D) and quasi-two-dimensional (q2D) binary colloid suspensions. The new results extend the findings of similar studies of one-component quasi-one-dimensional and quasi-two-dimensional colloid suspensions. Our principal new finding is that the presence of the smaller diameter component can destroy the oscillatory structure of the separation dependence of the q2D relative pair diffusion coefficient of the large particles even though the oscillatory character of the large particle equilibrium pair correlation function remains prominent, and that no such effect occurs with the q1D suspension. An interpretation of these results is proposed.
作者报告了在准一维(q1D)和准二维(q2D)二元胶体悬浮液中质心和相对对扩散系数的测量结果。这些新结果扩展了对单组分准一维和准二维胶体悬浮液类似研究的发现。我们主要的新发现是,即使大颗粒平衡对关联函数的振荡特性仍然很突出,但较小直径组分的存在会破坏大颗粒的q2D相对对扩散系数的分离依赖性的振荡结构,而q1D悬浮液不会出现这种效应。本文提出了对这些结果的一种解释。