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基于编织结构的超疏水表面设计

Design of a superhydrophobic surface using woven structures.

作者信息

Michielsen Stephen, Lee Hoon J

机构信息

College of Textiles, North Carolina State University, 2401 Research Drive, Raleigh, North Carolina 27695-8301, USA.

出版信息

Langmuir. 2007 May 22;23(11):6004-10. doi: 10.1021/la063157z. Epub 2007 Apr 28.

Abstract

The relationship between surface tension and roughness is reviewed. The Cassie-Baxter model is restated in its original form, which better describes the most general cases of surface roughness. Using mechanical and chemical surface modification of nylon 6,6 woven fabric, an artificial superhydrophobic surface was prepared. A plain woven fabric mimicking the Lotus leaf was created by further grafting 1H,1H-perfluorooctylamine or octadecylamine to poly(acrylic acid) chains which had previously been grafted onto a nylon 6,6 woven fabric surface. Water contact angles as high as 168 degrees were achieved. Good agreement between the predictions based on the original Cassie-Baxter model and experiments was obtained. The version of the Cassie-Baxter model in current use could not be applied to this problem since the surface area fractions in this form is valid only when the liquid is in contact with a flat, porous surface. The angle at which a water droplet rolls off the surface has also been used to define a superhydrophobic surface. It is shown that the roll-off angle is highly dependent on droplet size. The roll-off angles of these superhydrophobic surfaces were less than 5 degrees when a 0.5 mL water droplet was applied.

摘要

综述了表面张力与粗糙度之间的关系。重新阐述了原始形式的卡西 - 巴克斯特模型,该模型能更好地描述表面粗糙度的最一般情况。通过对尼龙6,6机织物进行机械和化学表面改性,制备了人工超疏水表面。通过将1H,1H - 全氟辛胺或十八烷基胺进一步接枝到先前已接枝到尼龙6,6机织物表面的聚丙烯酸链上,制备了一种模仿荷叶的平纹机织物。实现了高达168度的水接触角。基于原始卡西 - 巴克斯特模型的预测与实验结果取得了良好的一致性。当前使用的卡西 - 巴克斯特模型版本不适用于此问题,因为这种形式的表面积分数仅在液体与平坦、多孔表面接触时才有效。水滴从表面滚落的角度也被用于定义超疏水表面。结果表明,滚落角高度依赖于液滴尺寸。当施加0.5 mL水滴时,这些超疏水表面的滚落角小于5度。

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