Omür-Ozbek P, Little J C, Dietrich A M
Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, 418 Durham Hall, Blacksburg, VA, 24061-0246, USA.
Water Sci Technol. 2007;55(5):249-56. doi: 10.2166/wst.2007.186.
The most common compounds responsible for off flavours are geosmin, 2-MIB, and nonadienal which are poorly removed by conventional water treatment operations and hence result in customer complaints. Because these odourants are moderately volatile and have very low odour threshold values, it is necessary to determine their concentrations in air when water is used indoors. If the detectable aqueous concentrations for these odourants are known, the utilities may take action to treat their water at times when the concentration of the raw water exceeds the threshold concentration. To predict the concentration in the shower stall and bathroom air after showering, recently published Henry's law constants for the selected odourants and a model developed to determine the volatilization of the odourous compounds by applying two-resistance theory were used. Then the results were compared with the odour threshold concentration data to determine under which conditions the odourants become detectable. For parameters representing a typical bathroom and shower stall setting, the results showed that the odourants become detectable when the aqueous concentration of geosmin and nonadienal exceed 10 ng/L at 42 degrees C. As the aqueous concentration increases, geosmin and nonadienal become detectable at lower temperatures, however 2-MIB is only detectable above 20 ng/L and at 42 degrees C.
造成异味的最常见化合物是土臭素、2-甲基异莰醇和壬二烯醛,传统水处理工艺很难去除这些化合物,因此会导致客户投诉。由于这些气味物质具有一定的挥发性且气味阈值非常低,因此在室内使用水时,有必要测定它们在空气中的浓度。如果已知这些气味物质的可检测水溶液浓度,当原水浓度超过阈值浓度时,公用事业公司可以采取措施处理其用水。为了预测淋浴后淋浴间和浴室空气中的浓度,使用了最近公布的所选气味物质的亨利定律常数以及一个通过应用双阻力理论来确定有气味化合物挥发情况而开发的模型。然后将结果与气味阈值浓度数据进行比较,以确定在哪些条件下气味物质可被检测到。对于代表典型浴室和淋浴间设置的参数,结果表明,当地中海素和壬二烯醛在42摄氏度时的水溶液浓度超过10纳克/升时,这些气味物质可被检测到。随着水溶液浓度的增加,土臭素和壬二烯醛在较低温度下即可被检测到,然而2-甲基异莰醇仅在高于20纳克/升且温度为42摄氏度时才可被检测到。