Raghu S, Ahmed Basha C
Central Electrochemical Research Institute, Karaikudi 630 006, Tamilnadu, India.
J Hazard Mater. 2007 Oct 22;149(2):324-30. doi: 10.1016/j.jhazmat.2007.03.087. Epub 2007 Apr 8.
This paper examines the use of chemical or electrocoagulation treatment process followed by ion-exchange process of the textile dye effluent. The dye effluent was treated using polymeric coagulant (cationic dye-fixing agent) or electrocoagulation (iron and aluminum electrode) process under various conditions such as various current densities and effect of pH. Efficiencies of COD reduction, colour removal and power consumption were studied for each process. The chemical or electrochemical treatment are indented primarily to remove colour and COD of wastewater while ion exchange is used to further improve the removal efficiency of the colour, COD, Fe concentration, conductivity, alkalinity and total dissolved solids (TDS). From the results chemical coagulation, maximum COD reduction of about 81.3% was obtained at 300 mg/l of coagulant whereas in electrocoagulation process, maximum COD removal of about 92.31% (0.25 A/dm2) was achieved with energy consumption of about 19.29 k Wh/kg of COD and 80% (1A/dm(2)) COD removal was obtained with energy consumption of about 130.095 k Wh/kg of COD at iron and aluminum electrodes, respectively. All the experimental results, throughout the present study, have indicated that chemical or electrocoagulation treatment followed by ion-exchange methods were very effective and were capable of elevating quality of the treated wastewater effluent to the reuse standard of the textile industry.
本文研究了采用化学或电凝聚处理工艺,随后进行离子交换工艺处理纺织染料废水的情况。在各种条件下,如不同电流密度和pH值的影响下,使用聚合混凝剂(阳离子固色剂)或电凝聚(铁和铝电极)工艺处理染料废水。研究了每个工艺的化学需氧量(COD)降低效率、脱色效率和能耗。化学或电化学处理主要旨在去除废水的颜色和COD,而离子交换则用于进一步提高颜色、COD、铁浓度、电导率、碱度和总溶解固体(TDS)的去除效率。从结果来看,化学混凝在投加300mg/l混凝剂时,COD最大降低约81.3%;而在电凝聚工艺中,在铁电极和铝电极处,分别在电流密度为0.25A/dm²时,COD最大去除约92.31%,能耗约为19.29kWh/kg COD,在电流密度为1A/dm²时,COD去除80%,能耗约为130.095kWh/kg COD。在整个本研究中,所有实验结果均表明,化学或电凝聚处理后再采用离子交换方法非常有效,能够将处理后的废水水质提升至纺织工业的回用标准。