Dinca-Panaitescu Mihaela, Li James, Dinca-Panaitescu Serban
Department of Civil Engineering, Ryerson University, 350 Victoria Street, Toronto, Ontario, Canada M5B 2K3, Canada.
J Hazard Mater. 2007 Nov 19;149(3):707-19. doi: 10.1016/j.jhazmat.2007.04.032. Epub 2007 Apr 19.
Accidents in urban areas involving chemical spills demands development of not only feasible emergency strategies, but also a consistent framework to protect the environment and prevent accidents. This can be possible only by a sound understanding of the environmental impact of spills and their potential long-term effects. Furthermore, the impact assessment of chemical spills can not be done disregarding the spatial-temporal pattern of previous exposures reciprocally influenced by both chemical and environmental properties. In this context, this paper presents an analysis framework to quantify the cumulative effects of chemical spills at any given point of a certain area based on a "present" history of exposure coupled with chemical and environmental properties to predict possible scenarios of future exposure and estimate in advance potential alarming levels of pollution. In the present circumstances when increasing knowledge is required for an accurate prediction of spill migration through unsaturated soil, this paper proposes an algorithm capable of incorporating models of increasing complexities to simulate the single-spill events once new advancements in the field are taken. The algorithm developed is illustrated using a simple model with homogenous and steady-state conditions to simulate the single-spill events. A hypothetical case study was constructed to illustrate the analysis steps and the benefits of the algorithm.
城市地区涉及化学品泄漏的事故不仅需要制定可行的应急策略,还需要一个统一的框架来保护环境和预防事故。只有充分了解泄漏对环境的影响及其潜在的长期影响,才有可能做到这一点。此外,化学品泄漏的影响评估不能忽视先前暴露的时空模式,而这种模式会受到化学性质和环境性质的相互影响。在此背景下,本文提出了一个分析框架,用于根据某一区域任何给定地点的“当前”暴露历史以及化学和环境性质,量化化学品泄漏的累积影响,以预测未来暴露的可能情况,并提前估计潜在的污染警报水平。在当前需要更多知识来准确预测化学品通过非饱和土壤迁移的情况下,本文提出了一种算法,一旦该领域有新进展,该算法能够纳入复杂度不断增加的模型来模拟单次泄漏事件。所开发的算法通过一个具有均匀和稳态条件的简单模型进行说明,以模拟单次泄漏事件。构建了一个假设案例研究来说明分析步骤和该算法的优势。