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蒸馏水从近红外区域到紫外区域的折射率测量。

Measurement of the refractive index of distilled water from the near-infrared region to the ultraviolet region.

作者信息

Daimon Masahiko, Masumura Akira

机构信息

Measurement Service Center, Ohara, Incoporated, Sagamihara-Shi, Kanagawa, Japan.

出版信息

Appl Opt. 2007 Jun 20;46(18):3811-20. doi: 10.1364/ao.46.003811.

Abstract

By the minimum deviation method using a prism shaped cell, the absolute refractive indices of high-performance liquid chromatography distilled water were measured at the wavelengths from 1129 to 182 nm, at the temperature of 19 degrees C, 21.5 degrees C, and 24 degrees C, and then dn/dt at 21.5 degrees C was calculated. The coefficients of the four-term Sellmeier dispersion formula were determined by using the refractive indices at each temperature. As a result of the comparison of our refractive index data in the visible wavelength region with the formula by Tilton et al. at the National Bureau of Standards in 1938, both the refractive index data corresponded within 6 x 10(-6). In the UV region, the absolute refractive index at 193.39 nm calculated by the data measured nearby the wavelengths from 200 to 190 nm was 1.436517 (21.5 degrees C). The value was lower by 9 x 10(-5) or 10 x 10(-5) than the data measured by Burnett et al. at the National Institute of Standards and Technology.

摘要

使用棱镜形样品池通过最小偏向角法,在19℃、21.5℃和24℃的温度下,测量了高效液相色谱蒸馏水在1129至182nm波长范围内的绝对折射率,然后计算了21.5℃时的dn/dt。利用各温度下的折射率确定了四项Sellmeier色散公式的系数。将我们在可见光波长区域的折射率数据与1938年美国国家标准局蒂尔顿等人的公式进行比较,两者折射率数据在6×10⁻⁶范围内相符。在紫外区域,根据在200至190nm波长附近测量的数据计算出的193.39nm处的绝对折射率为1.436517(21.5℃)。该值比美国国家标准与技术研究院伯内特等人测量的数据低9×10⁻⁵或10×10⁻⁵。

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