Su Yao-dong, Hao Bing-bing, Qin Li-jun, Gan Li-hua
Department of Chemistry, Tongji University, Shanghai 200092, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2007 Mar;27(3):589-91.
A method was proposed for the determination of trace copper and lead in beer with flame atomic absorption spectrometry after preconcentration of copper and lead by rapid coprecipitation technique with 8-oxyquinoline-Mg(II) using manganese as an internal standard at pH 9. The standard addition recovery of lead is between 97.6%-103.0%. The detection limit is 6.28 x 10(-3) microg x mL(-1) for copper and 2.26 x 10(-2) microg x mL(-1) for lead when the sample volume is 100 mL. The effect of matrix can be overcome by the method and the results are satisfying. The method proposed here is rapid and has good reproducibility.
提出了一种用火焰原子吸收光谱法测定啤酒中痕量铜和铅的方法。该方法在pH 9的条件下,以锰为内标,采用8-羟基喹啉-Mg(II)快速共沉淀技术对铜和铅进行预富集。铅的标准加入回收率在97.6%-103.0%之间。当样品体积为100 mL时,铜的检出限为6.28×10(-3) μg·mL(-1),铅的检出限为2.26×10(-2) μg·mL(-1)。该方法可克服基体效应,结果令人满意。所提出的方法快速且具有良好的重现性。