Two frustrated, bitetrahedral single-molecule magnets.
作者信息
Milios Constantinos J, Gass Ian A, Vinslava Alina, Budd Laura, Parsons Simon, Wernsdorfer Wolfgang, Perlepes Spyros P, Christou George, Brechin Euan K
机构信息
School of Chemistry, The University of Edinburgh, Edinburgh, UK.
出版信息
Inorg Chem. 2007 Aug 6;46(16):6215-7. doi: 10.1021/ic7006638. Epub 2007 Jul 3.
PMID:17608417
Abstract
Two unusual mixed-valent {MnIII6MnII} bitetrahedra display frustrated magnetic exchange, leading to S = 13/2 +/- 1 and 11/2 +/- 1 ground states and slow magnetization relaxation.
摘要
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